The gold–sulfur interface at the nanoscale-- Main. The covalent bond between gold and sulfur gives rise to a robust but modifiable interaction that is of paramount importance in : Hannu Hkkinen
The gold-sulfur interface at the nanoscale - PubMed-- The gold-sulfur interface at the nanoscale Nat Chem. May ;():-. doi: ./nchem.. Author Hannu Hkkinen considerable experimental and : Hannu Hkkinen
The gold-sulfur interface at the nanoscale - ResearchGate: : Hannu Hkkinen: Download Citation | The gold-sulfur interface at the nanoscale | Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of organic molecules on
The gold-sulfur interface at the nanoscale. | Semantic Scholar-- The gold-sulfur interface at the nanoscale. Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of organic molecules on gold, for
The gold–sulfur interface at the nanoscale - typeset.io-- Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of organic molecules on gold, for passivated gold nanoclusters and for
The gold–sulfur interface at the nanoscale-- Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of organic molecules on gold, The gold–sulfur interface at the nanoscale.
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Properties of the gold–sulphur interface: from self -- Introduction Self-assembled monolayers (SAMs) of thiolates on gold surfaces have found applications in fields such as sensing, molecular electronics and surface
Altmetric – The gold–sulfur interface at the nanoscaleThe gold–sulfur interface at the nanoscale Published in: Nature Chemistry, May DOI: ./nchem.: Pubmed ID:. Authors: Hannu Hkkinen Abstract:
Sulfur-doped graphene anchoring of ultrafine Au-- We demonstrate herein that chemical dopants on sulfur-doped graphene (S-G) can be utilized to stabilize ultrafine (sub- nm) Au(PET) clusters to enable stable
The gold–sulfur interface at the nanoscale - typeset.io-- Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of organic molecules on gold, for passivated gold nanoclusters and for molecule-gold junctions, are archetypal systems in various fields of current nanoscience research, materials science, inorganic chemistry and surface science. Understanding this
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Altmetric – The gold–sulfur interface at the nanoscaleThe gold–sulfur interface at the nanoscale Published in: Nature Chemistry, May DOI: ./nchem.: Pubmed ID:. Authors: Hannu Hkkinen Abstract: Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of organic molecules on gold, for passivated gold nanoclusters and for molecule-gold
Browse Articles | Nature Chemistry-- The gold–sulfur interface at the nanoscale Thiolate-protected gold surfaces and interfaces are archetypal systems in various fields of current research in nanoscience, materials science
Ligand exchange reactions on thiolate-protected gold The chemical properties and flexibility of the gold–sulfur interface, as discussed above, form the basis for the post-synthesis modification and further functionalization of the gold nanoclusters. Among them, ligand exchange reaction is extraordinarily sparkly and we will now focus on this topic in the following sections.
A halogen-free synthesis of gold nanoparticles using -- The gold-sulfur interface at the nanoscale. Nat Chem. ; :–. doi: ./nchem.. [Google Scholar] Hiramatsu H, Osterloh FE. A simple large-scale synthesis of nearly monodisperse gold and silver nanoparticles with adjustable sizes and with exchangeable surfactants. Chem Mater. ;
Gold nanoparticles functionalization notably decreases -- Considering the strength of sulfur bonding with gold, thiolated-PEG is often selected as a strategic ligand anchoring. Nevertheless, sulfur groups are known to be good hydroxyl radical scavengers. The gold-sulfur interface at the nanoscale. Nat. Chem., (), pp. -. CrossRef Google Scholar. S. Link, M.A. El-Sayed.
Exceptional oxidation activity with size-controlled Financial support from the Spanish Science and Innovation Ministry (Consolider Ingenio -MULTICAT CSD-, Subprograma de apoyo a Centros y Universidades de Excelencia Severo Ochoa SEV , MAT- and MAT- projects) and Xunta de Galicia (Grupos Ref.Comp./) is acknowledged. M.J.Y. and E. L.
High-resolution crystal structure of a kDa -- Introduction. Gold nanoclusters (AuNC) with atomically precise sizes represent a distinct class of nanomaterials that can be identified by a single chemical formula, [Au n (L) m] q, and exhibit molecule-like electronic and optical properties , .Such a unique set of features in a nanoscale system has been rationalized as the result of the ‘size
Nanomaterials | Free Full-Text | Interaction of Colloidal We hypothesize that the adsorption of these proteins was due to their high sulfur content, allowing for their interaction with gold nanoparticles via the Au-S bond. Interfaces , , –. [Google Scholar] W. BSA modification to reduce CTAB induced nonspecificity and cytotoxicity of aptamer-conjugated gold nanorods. Nanoscale
The gold–sulfur interface at the nanoscale - -- Functionalization of Inorganic Nanoparticles for Bioimaging Applications. The gold–sulfur interface at the nanoscale. Monolayer coated gold nanoparticles for delivery applications. Surface functionalization of gold nanoparticles for targeted drug delivery. ChemInform Abstract: Role of Functionalization: Strategies to Explore Potential Nano
The gold-sulfur interface at the nanoscale - During the past five years, considerable experimental and theoretical advances have furthered our understanding of the molecular structure of the gold-sulfur interface in these systems. This Review discusses the recent progress from the viewpoint of theory and computations, with connections to relevant experiments.
The gold–sulfur interface at the nanoscale-- Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of organic molecules on gold, The gold–sulfur interface at the nanoscale. Hkkinen, Hannu; Closed Access . Published: May ; Publisher: Springer Science and Business Media LLC ;
(PDF) The Chemistry of the Sulfur–Gold Interface: In Search Self-assembled monolayers of -octanethiol (OT-SAMs) on Au() substrates prepared using ethanol, N,N′-dimethylformamide (DMF), toluene, or hexane were examined using scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS) to investigate the effects of the solvent on the molecular packing at high solution
Ligand exchange reactions on thiolate-protected gold The chemical properties and flexibility of the gold–sulfur interface, as discussed above, form the basis for the post-synthesis modification and further functionalization of the gold nanoclusters. Among them, ligand exchange reaction is extraordinarily sparkly and we will now focus on this topic in the following sections.
Correlating the Influence of Disulfides in Monolayers The gold–sulfur interface at the nanoscale. Nat. Chem. , , – , DOI: ./nchem. considerable experimental and theoretical advances have furthered our understanding of the molecular structure of the gold-sulfur interface in these systems. This Review discusses the recent progress from the viewpoint of theory and
The chemistry of the sulfur-gold interface: in search of a -- In many applications, the structure and chemistry of the sulfur-gold interface become crucial since they control the system properties. Therefore, many researchers have focused on understanding of the nature of this interface on both planar and nanoparticle thiol-covered surfaces. The gold-sulfur interface at the nanoscale. Hkkinen H. Nat
The gold-sulfur interface at the nanoscale. H. Hkkinen, , Nature chemistry. Mixed-Monolayer-Protected Au Clusters with Bulky Calix[]arene Functionalities. H. Hkkinen, T. Pradeep, H. Tenhu, , The journal
A halogen-free synthesis of gold nanoparticles using -- The gold-sulfur interface at the nanoscale. Nat Chem. ; :–. doi: ./nchem.. [Google Scholar] Hiramatsu H, Osterloh FE. A simple large-scale synthesis of nearly monodisperse gold and silver nanoparticles with adjustable sizes and with exchangeable surfactants. Chem Mater. ;
Unraveling structures of protection ligands on gold -- Abstract. New low-energy atomic structures of the thiolate-protected gold nanoparticle Au (SH) are uncovered, where the atomic positions of the Au atoms are taken from the recent single-particle transmission electron microscopy measurement by Kornberg and co-workers, whereas the pattern of thiolate ligands on the gold core is